Extremely Narrow-Dispersed High Molecular Weight Polyethylene from Living Polymerization at Elevated Temperatures with o-F Substituted Ti Enolatoimines.
The article analyzes a study on elevated temperature polymerization techniques with o-F substitution in Ti complexes. Living polymerization is an essential tool for the synthesis of polymers and requires the absence of chain termination and irreversible transfer. Restrictions on catalyst activity an...
| Publicado en: | Journal of the American Chemical Society Vol. 130; no. 40; pp. 13204 - 13206 |
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| Autores principales: | , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
10/8/2008
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| Sumario: | The article analyzes a study on elevated temperature polymerization techniques with o-F substitution in Ti complexes. Living polymerization is an essential tool for the synthesis of polymers and requires the absence of chain termination and irreversible transfer. Restrictions on catalyst activity and molecular weights in polymerization at low temperatures were sought to be minimized in the study. Comparison of results by varying reaction conditions are also discussed. |
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