Extremely Narrow-Dispersed High Molecular Weight Polyethylene from Living Polymerization at Elevated Temperatures with o-F Substituted Ti Enolatoimines.

The article analyzes a study on elevated temperature polymerization techniques with o-F substitution in Ti complexes. Living polymerization is an essential tool for the synthesis of polymers and requires the absence of chain termination and irreversible transfer. Restrictions on catalyst activity an...

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Publicado en:Journal of the American Chemical Society Vol. 130; no. 40; pp. 13204 - 13206
Autores principales: Sze-Man Yu, Mecking, Stefan
Formato: Artículo
Publicado: American Chemical Society 10/8/2008
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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        atl: Extremely Narrow-Dispersed High Molecular Weight Polyethylene from Living Polymerization at Elevated Temperatures with o-F Substituted Ti Enolatoimines.
      aug:
        au:
          Sze-Man Yu
          Mecking, Stefan
        affil: University of Konstanz, Chair of Chemical Materials Science, Department of Chemistry, Universitatsstr. 10, D-78457 Konstanz, Germany
      su:
        Polymerization
        Polymers
        Alkenes
        Organotitanium compounds
        High temperatures
        Catalysis
      sug:
        subj:
          Polymerization
          Polymers
          Alkenes
          Organotitanium compounds
          High temperatures
          Catalysis
      ab: The article analyzes a study on elevated temperature polymerization techniques with o-F substitution in Ti complexes. Living polymerization is an essential tool for the synthesis of polymers and requires the absence of chain termination and irreversible transfer. Restrictions on catalyst activity and molecular weights in polymerization at low temperatures were sought to be minimized in the study. Comparison of results by varying reaction conditions are also discussed.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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