Key Role of Ti(IV) in the Selective Radical-Radical Cross-Coupling Mediated by the lngold-Fischer Effect.
We report an innovative approach for the selective synthesis of polyfunctional derivatives by cross-combination of different radicals generated under mild conditions. The coordinating effect of Ti(IV) plays a key role in the reaction mechanism: due to its chelating action on the hydroxyl groups, it...
| Publicado en: | Journal of the American Chemical Society Vol. 130; no. 52; pp. 18018 - 18025 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
12/31/2008
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |