Key Role of Ti(IV) in the Selective Radical-Radical Cross-Coupling Mediated by the lngold-Fischer Effect.

We report an innovative approach for the selective synthesis of polyfunctional derivatives by cross-combination of different radicals generated under mild conditions. The coordinating effect of Ti(IV) plays a key role in the reaction mechanism: due to its chelating action on the hydroxyl groups, it...

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Publicado en:	Journal of the American Chemical Society Vol. 130; no. 52; pp. 18018 - 18025
Autores principales:	Spaccini, Raffaele, Pastori, Nadia, Clerici, Angelo, Punta, Carlo, Porta, Ombretta
Formato:	Artículo
Publicado:	American Chemical Society 12/31/2008
Materias:	Chemistry Ketones Hydroxylation Chemical reactions Hydroformylation
Acceso en línea:	Ver este registro en EBSCOhost