Mechanistic Insights into Catalytic H Oxidation by Ni Complexes Containing a Diphosphine Ligand with a Positioned Amine Base.

The mixed-ligand complex [Ni(dppp)(PN)](BF), 3, (where PN is 1,5-dibenzyl-3,7- diphenyl-1,5-diaza-3,7-diphosphacyclooctane and dppp is 1,3-bis(diphenylphosphino)propane) has been synthesized. Treatment of this complex with H and triethylamine results in the formation of the Ni complex, Ni(dppp)(PN),...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 131; no. 16; pp. 5935 - 5946
Main Authors:	Yang, Jenny Y., Bullock, R. Morris, Shaw, Wendy J., Twamley, Brendan, Fraze, Kendra, DuBois, M. Rakowski, DuBois, Daniel L.
Format:	Article
Published:	American Chemical Society 4/29/2009
Subjects:	Ligands (Chemistry) Amines X-ray research Optical diffraction Atoms
Online Access:	View this record in EBSCOhost