Charge Density Analysis of the (C—C)→Ti Agostic Interactions in a Titanacyclobutane Complex.

The experimental electron density study of Ti(CHMe)[(CH)CMe] provides direct evidence for the presence of (C—C)→Ti agostic interactions. In accord with the model of Scherer and McGrady, the C—C bond densities no longer show cylindrical symmetry in the vicinity of the Ti atom and differ markedly from...

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Publicado en:	Journal of the American Chemical Society Vol. 131; no. 17; pp. 6154 - 6161
Autores principales:	Scheins, Stephan, Messerschmidt, Marc, Gembicky, Milan, Pitak, Mateusz, Volkov, Anatoliy, Coppens, Philip, Harvey, Benjamin G., Turpin, Gregory C., Arif, Atta M., Ernst, Richard D.
Formato:	Artículo
Publicado:	American Chemical Society 5/6/2009
Materias:	Electron distribution Symmetry (Musical composition) Electron configuration Solid state physics Chemical reactions
Acceso en línea:	Ver este registro en EBSCOhost