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Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(ll) Complexes.

The article discusses the complexes of the first carbonare-based pincer ligand family metalated with palladium (Pd). It refers to the density functional theory (DFT) calculations, indicating that the electronic structure of the complex derived from the new ligand is separated from its hydrocarbon an...

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Published in:Journal of the American Chemical Society Vol. 131; no. 27; pp. 9482 - 9484
Main Authors: Spokoyny, Alexander M., Reuter, Matthew G., Stern, Charlotte L., Ratner, Mark A., Seideman, Tamar, Mirkin, Chad A.
Format: Article
Published: American Chemical Society 7/15/2009
Subjects:
Palladium
Ligands (Chemistry)
Density functionals
Electronic structure
Hydrocarbons
Molecular structure
X-ray diffraction
Biochemistry
Online Access:View this record in EBSCOhost
Summary:The article discusses the complexes of the first carbonare-based pincer ligand family metalated with palladium (Pd). It refers to the density functional theory (DFT) calculations, indicating that the electronic structure of the complex derived from the new ligand is separated from its hydrocarbon analogues. It defines the solid-state molecular structure of the complex using the single crystal X-ray diffraction methods. Insights from the preliminary DFT calculations are provided.