X-ray Emission Spectroscopy To Study Ligand Valence Orbitals in Mn Coordination Complexes.

We discuss a spectroscopic method to determine the character of chemical bonding and for the identification of metal ligands in coordination and bioinorganic chemistry. It is based on the analysis of satellite lines in X-ray emission spectra that arise from transitions between valence orbitals and t...

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Publicado en:	Journal of the American Chemical Society Vol. 131; no. 36; pp. 13161 - 13168
Autores principales:	Smolentsev, Grigory, Soldatov, Alexander V., Messinger, Johannes, Merz, Kathrin, Weyhermüller, Thomas, Bergmann, Uwe, Pushkar, Yulia, Junko, Junko, Yachandra, Vittal K., Glatzel, Pieter
Formato:	Artículo
Publicado:	American Chemical Society 9/16/2009
Materias:	X-ray spectroscopy Ligands (Chemistry) Manganese Density functionals Chemical research
Acceso en línea:	Ver este registro en EBSCOhost