X-ray Emission Spectroscopy To Study Ligand Valence Orbitals in Mn Coordination Complexes.

We discuss a spectroscopic method to determine the character of chemical bonding and for the identification of metal ligands in coordination and bioinorganic chemistry. It is based on the analysis of satellite lines in X-ray emission spectra that arise from transitions between valence orbitals and t...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 131; no. 36; pp. 13161 - 13168
Main Authors:	Smolentsev, Grigory, Soldatov, Alexander V., Messinger, Johannes, Merz, Kathrin, Weyhermüller, Thomas, Bergmann, Uwe, Pushkar, Yulia, Junko, Junko, Yachandra, Vittal K., Glatzel, Pieter
Format:	Article
Published:	American Chemical Society 9/16/2009
Subjects:	X-ray spectroscopy Ligands (Chemistry) Manganese Density functionals Chemical research
Online Access:	View this record in EBSCOhost