Weakening C-O Bonds: Ti(III), a New Reagent for Alcohol Deoxygenation and Carbonyl Coupling Olefination.

Investigations detailed herein, including density functional theory (DFT) calculations, demonstrate that the formation of either alkoxy- or hydroxy-Ti(lll) complexes considerably decreases the energy of activation for C-O bond homolysis. As a consequence of this observation, we described two new syn...

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Publicado en:	Journal of the American Chemical Society Vol. 132; no. 1; pp. 254 - 260
Autores principales:	Diéguez, Horacio A., López, Armando, Domingo, Victoriano, Arteaga, Jesús F., Dobado, José A., Herrador, M. Mar, QuíIez del Moral, José F., Barrero, Alejandro F.
Formato:	Artículo
Publicado:	American Chemical Society 1/13/2010
Materias:	Titanium Metal complexes Carbon Oxygen Alcohols (Chemical class) Carbonyl compounds Density functionals Organic chemistry
Acceso en línea:	Ver este registro en EBSCOhost