Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity.

The article discusses the demonstration of a synthetic strategy to create metal-organic frameworks (MOFs) for the generation of aromatic walls and rigid metal-organic pillars with the application of two different organic connectors. It says that dimethyformamide (DMF) solvents of the reaction which...

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Publicado en:Journal of the American Chemical Society Vol. 132; no. 8; pp. 2561 - 2564
Autores principales: Ming-Hua Zeng, Qiang-Xin Wang, Yan-Xi Tan, Sheng Hu, Hai-Xia Zhao, La-Sheng Long, Kurmoo, Mohamedally
Formato: Artículo
Publicado: American Chemical Society 3/3/2010
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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        atl: Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity.
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          Ming-Hua Zeng
          Qiang-Xin Wang
          Yan-Xi Tan
          Sheng Hu
          Hai-Xia Zhao
          La-Sheng Long
          Kurmoo, Mohamedally
        affil:
          Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education), School of Chemistry & Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China
          State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
          Laboratoire de Chimie de Coordination Organique, CNRS-UMR7I4O, Université de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg Cedex, France
      su:
        Metals
        Structural frames
        Dimethylformamide
        Methanol
        Porous materials
        Crystal whiskers
      sug:
        subj:
          Metals
          Structural frames
          Dimethylformamide
          Methanol
          Porous materials
          Crystal whiskers
      ab: The article discusses the demonstration of a synthetic strategy to create metal-organic frameworks (MOFs) for the generation of aromatic walls and rigid metal-organic pillars with the application of two different organic connectors. It says that dimethyformamide (DMF) solvents of the reaction which can be replaced for methanol were housed by square-shaped channels. Moreover, highly-stable MOFs were constructed with rigid metal-organic pillars associated by organic groups to create double walls.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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