Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity.

The article discusses the demonstration of a synthetic strategy to create metal-organic frameworks (MOFs) for the generation of aromatic walls and rigid metal-organic pillars with the application of two different organic connectors. It says that dimethyformamide (DMF) solvents of the reaction which...

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Detalles Bibliográficos
Publicado en:	Journal of the American Chemical Society Vol. 132; no. 8; pp. 2561 - 2564
Autores principales:	Ming-Hua Zeng, Qiang-Xin Wang, Yan-Xi Tan, Sheng Hu, Hai-Xia Zhao, La-Sheng Long, Kurmoo, Mohamedally
Formato:	Artículo
Publicado:	American Chemical Society 3/3/2010
Materias:	Metals Structural frames Dimethylformamide Methanol Porous materials Crystal whiskers
Acceso en línea:	Ver este registro en EBSCOhost

Descripción
Sumario:	The article discusses the demonstration of a synthetic strategy to create metal-organic frameworks (MOFs) for the generation of aromatic walls and rigid metal-organic pillars with the application of two different organic connectors. It says that dimethyformamide (DMF) solvents of the reaction which can be replaced for methanol were housed by square-shaped channels. Moreover, highly-stable MOFs were constructed with rigid metal-organic pillars associated by organic groups to create double walls.