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Rigid Pillars and Double Walls in a Porous Metal-Organic Framework: Single-Crystal to Single-Crystal, Controlled Uptake and Release of Iodine and Electrical Conductivity.

The article discusses the demonstration of a synthetic strategy to create metal-organic frameworks (MOFs) for the generation of aromatic walls and rigid metal-organic pillars with the application of two different organic connectors. It says that dimethyformamide (DMF) solvents of the reaction which...

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Published in:Journal of the American Chemical Society Vol. 132; no. 8; pp. 2561 - 2564
Main Authors: Ming-Hua Zeng, Qiang-Xin Wang, Yan-Xi Tan, Sheng Hu, Hai-Xia Zhao, La-Sheng Long, Kurmoo, Mohamedally
Format: Article
Published: American Chemical Society 3/3/2010
Subjects:
Metals
Structural frames
Dimethylformamide
Methanol
Porous materials
Crystal whiskers
Online Access:View this record in EBSCOhost
Summary:The article discusses the demonstration of a synthetic strategy to create metal-organic frameworks (MOFs) for the generation of aromatic walls and rigid metal-organic pillars with the application of two different organic connectors. It says that dimethyformamide (DMF) solvents of the reaction which can be replaced for methanol were housed by square-shaped channels. Moreover, highly-stable MOFs were constructed with rigid metal-organic pillars associated by organic groups to create double walls.