Mechanistic Insights into Alkene Epoxidation with HO by Ti- and other TM-Containing Polyoxometalates: Role of the Metal Nature and Coordination Environment.
The oxidation of alkenes by HO catalyzed by Ti(IV)-containing polyoxometalates (POMs) as models of Ti single-site catalysts has been investigated at DFT level and has been compared with other early transition-metal-substituted polyoxometalates. We have studied in detail the reaction mechanism of the...
| Publicado en: | Journal of the American Chemical Society Vol. 132; no. 21; pp. 7488 - 7498 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
6/2/2010
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |