Mechanistic Insights into Alkene Epoxidation with HO by Ti- and other TM-Containing Polyoxometalates: Role of the Metal Nature and Coordination Environment.

The oxidation of alkenes by HO catalyzed by Ti(IV)-containing polyoxometalates (POMs) as models of Ti single-site catalysts has been investigated at DFT level and has been compared with other early transition-metal-substituted polyoxometalates. We have studied in detail the reaction mechanism of the...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 132; no. 21; pp. 7488 - 7498
Main Authors:	Antonova, Nadya S., Carbó, Jorge J., Kortz, Ulrich, KhoIdeeva, Oxana A., Poblet, Josep M.
Format:	Article
Published:	American Chemical Society 6/2/2010
Subjects:	Alkenes Polyoxometalates Catalysts Titanium Oxidation-reduction reaction Epoxy compounds
Online Access:	View this record in EBSCOhost