Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures.
A β,β'-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligopor- phyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce t...
| Publicado en: | Journal of the American Chemical Society Vol. 132; no. 34; pp. 11868 - 11870 |
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| Autores principales: | , , , , , |
| Formato: | Artículo |
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American Chemical Society
9/1/2010
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=53431245&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 53431245 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 9/1/2010 vid: 132 iid: 34 pid: 997 pub: American Chemical Society artinfo: ui: 53431245 10.1021/ja1046654 ppf: 11868 ppct: 2 formats: tig: atl: Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures. aug: au: Jianxin Song Aratani, Naoki Ji Haeng Heo Dongho Kim Shinokubo, Hiroshi Osuka, Atsuhiro affil: Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan PRESTO, Japan Science and Technology Agency, Spectroscopy Laboratory for Functional π-Electronic Systems, Seoul 120-749, Korea Department of Chemistry, Yonsei University, Seoul 120-749, Korea Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 463-8603, Japan su: Porphyrins Hydrogen bonding Palladium Nitrogen Optical diffraction Ultraviolet radiation sug: subj: Porphyrins Hydrogen bonding Palladium Nitrogen Optical diffraction Ultraviolet radiation ab: A β,β'-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligopor- phyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce the corresponding Pd(II) complexes, which display even larger bent structures and larger TPA values at 800 nm. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2010 holdings: @attributes: islocal: N |
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