Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures.
A β,β'-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligopor- phyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce t...
| Publicado en: | Journal of the American Chemical Society Vol. 132; no. 34; pp. 11868 - 11870 |
|---|---|
| Autores principales: | , , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
9/1/2010
|
| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |