A New in Situ Optical Microscope with Single Atomic Layer Resolution for Observation of Electrochemical Dissolution of Au(111).
Monatomic steps with a height of 0.25 nm on ultraflat Au(1 11) surfaces during electrôchemical dissolution can be seen for the first time by a laser confocal microscope combined with a differential interference contrast microscope (LCM-DIM). Atomic force microscopy images were acquired in the same a...
| Publicado en: | Journal of the American Chemical Society Vol. 132; no. 39; pp. 13657 - 13660 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
10/6/2010
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| Sumario: | Monatomic steps with a height of 0.25 nm on ultraflat Au(1 11) surfaces during electrôchemical dissolution can be seen for the first time by a laser confocal microscope combined with a differential interference contrast microscope (LCM-DIM). Atomic force microscopy images were acquired in the same area in order to confirm that the step lines observed by LCM-DIM are mostly monatomic steps with the height of 0.25 nm. Successively recorded LCM-DIM images indicated that the anodic dissolution of Au(1 11) takes place only at step edges in solutions containing chloride anions at potentials near the onset of anodic current. |
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