A New in Situ Optical Microscope with Single Atomic Layer Resolution for Observation of Electrochemical Dissolution of Au(111).

Monatomic steps with a height of 0.25 nm on ultraflat Au(1 11) surfaces during electrôchemical dissolution can be seen for the first time by a laser confocal microscope combined with a differential interference contrast microscope (LCM-DIM). Atomic force microscopy images were acquired in the same a...

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Publicado en:Journal of the American Chemical Society Vol. 132; no. 39; pp. 13657 - 13660
Autores principales: Wen, Rui, Lahiri, Abhishek, Azhagurajan, Mukkannan, Kobayashi, Shin-ichiro, Itaya, Kingo
Formato: Artículo
Publicado: American Chemical Society 10/6/2010
Materias:
Acceso en línea:Ver este registro en EBSCOhost
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      dt: 10/6/2010
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      pub: American Chemical Society
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        10.1021/Ja106231x
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        atl: A New in Situ Optical Microscope with Single Atomic Layer Resolution for Observation of Electrochemical Dissolution of Au(111).
      aug:
        au:
          Wen, Rui
          Lahiri, Abhishek
          Azhagurajan, Mukkannan
          Kobayashi, Shin-ichiro
          Itaya, Kingo
        affil:
          World Premier International Research Center, Advanced Institute for Materials Research (WPI-AIMR), Tohoku Universirt, Katahira 2-1-I, Aobaku, Sendai 980-8577, Japan
          Department of Applied Chemistry, Graduate School of Engineering, Tohoku University, 6-6-04 Aoba, Sendai 980-8579, Japan
      su:
        Electrochemistry
        Gold
        Atomic force microscopy
        Confocal microscopy
        Imaging systems
        Chlorides
      sug:
        subj:
          Electrochemistry
          Gold
          Atomic force microscopy
          Confocal microscopy
          Imaging systems
          Chlorides
      ab: Monatomic steps with a height of 0.25 nm on ultraflat Au(1 11) surfaces during electrôchemical dissolution can be seen for the first time by a laser confocal microscope combined with a differential interference contrast microscope (LCM-DIM). Atomic force microscopy images were acquired in the same area in order to confirm that the step lines observed by LCM-DIM are mostly monatomic steps with the height of 0.25 nm. Successively recorded LCM-DIM images indicated that the anodic dissolution of Au(1 11) takes place only at step edges in solutions containing chloride anions at potentials near the onset of anodic current.
      pubtype: Academic Journal
      doctype: Article
      src: R
    language: English
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