Ferric Superoxide and Ferric Hydroxide Are Used in the Catalytic Mechanism of Hydroxyethylphosphonate Dioxygenase: A Density Functional Theory Investigation.
Hydroxyethylphosphonate dioxygenase (HEPD) is a mononuclear nonheme iron enzyme that utilizes an O molecule to cleave a C—C bond in 2-hydroxyethylphosphonate and produce hydroxymethylphosphonate (HMP) and formic acid. Density functional theory calculations were performed on an enzyme active-site mod...
| Publicado en: | Journal of the American Chemical Society Vol. 132; no. 50; pp. 17901 - 17910 |
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| Autores principales: | , |
| Formato: | Artículo |
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American Chemical Society
12/22/2010
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| Acceso en línea: | Ver este registro en EBSCOhost |