"Nanoscale Lattice Fence" in a Metal-Organic Framework: Interplay between Hinged Topology and Highly Anisotropic Thermal Response.
A thermoresponsive, 3D hinged metal-organic framework (HMOF-1) assembled from meso-tetra(4-pyridyl)porphine and CdI exhibits a 3D "lattice fence" topology with extraordinary thermal expansion and shrinkage. A simple structural model is established to elucidate such a drastic thermal response. The hi...
| Publicado en: | Journal of the American Chemical Society Vol. 133; no. 38; pp. 14848 - 14852 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
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American Chemical Society
9/28/2011
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=66649991&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 66649991 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 9/28/2011 vid: 133 iid: 38 pid: 997 pub: American Chemical Society artinfo: ui: 66649991 10.1021/ja2032822 ppf: 14848 ppct: 4 formats: tig: atl: "Nanoscale Lattice Fence" in a Metal-Organic Framework: Interplay between Hinged Topology and Highly Anisotropic Thermal Response. aug: au: DeVries, Lucas D. Barron, Paul M. Hurley, Evan P. Chunhua Hu Wonyoung Choe affil: Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, United States Department of Chemistry, New York University, New York, New York 10003-6688, United States Nebraska Center for Materials and Nanoscience, University of Nebraska-Lincoln, Lincoln, Nebraska 68588-0304, United States su: Anisotropy Lattice dynamics Thermal expansion Structural frame models Topology sug: subj: Anisotropy Lattice dynamics Thermal expansion Structural frame models Topology ab: A thermoresponsive, 3D hinged metal-organic framework (HMOF-1) assembled from meso-tetra(4-pyridyl)porphine and CdI exhibits a 3D "lattice fence" topology with extraordinary thermal expansion and shrinkage. A simple structural model is established to elucidate such a drastic thermal response. The hinged structure model presented here can also be applied to other "lattice fence" topologies with little or no modification, depending on the symmetry of the molecular building blocks. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2011 holdings: @attributes: islocal: N |
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