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"Nanoscale Lattice Fence" in a Metal-Organic Framework: Interplay between Hinged Topology and Highly Anisotropic Thermal Response.

A thermoresponsive, 3D hinged metal-organic framework (HMOF-1) assembled from meso-tetra(4-pyridyl)porphine and CdI exhibits a 3D "lattice fence" topology with extraordinary thermal expansion and shrinkage. A simple structural model is established to elucidate such a drastic thermal response. The hi...

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Published in:Journal of the American Chemical Society Vol. 133; no. 38; pp. 14848 - 14852
Main Authors: DeVries, Lucas D., Barron, Paul M., Hurley, Evan P., Chunhua Hu, Wonyoung Choe
Format: Article
Published: American Chemical Society 9/28/2011
Subjects:
Anisotropy
Lattice dynamics
Thermal expansion
Structural frame models
Topology
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