Molecular Complexity via C-H Activation: A Dehydrogenative Diels-Alder Reaction.
Traditionally, C-H oxidation reactions install oxidized functionality onto a preformed molecular skeleton, resulting in a local molecular change. The use of C-H activation chemistry to construct complex molecular scaffolds is a new area with tremendous potential in synthesis. We report a Pd(II)/bis-...
| Publicado en: | Journal of the American Chemical Society Vol. 133; no. 38; pp. 14892 - 14896 |
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| Autores principales: | , |
| Formato: | Artículo |
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American Chemical Society
9/28/2011
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=66650002&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 66650002 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 9/28/2011 vid: 133 iid: 38 pid: 997 pub: American Chemical Society artinfo: ui: 66650002 10.1021/ja2059704 ppf: 14892 ppct: 4 formats: tig: atl: Molecular Complexity via C-H Activation: A Dehydrogenative Diels-Alder Reaction. aug: au: Stang, Erik M. White, M. Christina affil: Roger Adams Laboratory, Department of Chemistry, University of Illinois, Urbana, Illinois 61801, United States su: Oxidation-reduction reaction Diels-Alder reaction Activation (Chemistry) Molecular structure Biocomplexity sug: subj: Oxidation-reduction reaction Diels-Alder reaction Activation (Chemistry) Molecular structure Biocomplexity ab: Traditionally, C-H oxidation reactions install oxidized functionality onto a preformed molecular skeleton, resulting in a local molecular change. The use of C-H activation chemistry to construct complex molecular scaffolds is a new area with tremendous potential in synthesis. We report a Pd(II)/bis-sulfoxide-catalyzed dehydrogenative Diels-Alder reaction that converts simple terminal olefins into complex cycloadducts in a single operation. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2011 holdings: @attributes: islocal: N |
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