Synthesis, Structure, and Reactivity of Carbene-Stabilized Phosphorus(III)-Centered Trications [LP].

Carbene-stabilized [LP] cations have been synthesized for the first time by a reaction between 1-chloro-2,3-bis(dialkylamino)cyclopropenium salts and P(SiMe). In addition, the first structural characterization of such an entity is reported. Consistent with the X-ray data, density functional calculat...

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Publicado en:	Journal of the American Chemical Society Vol. 133; no. 51; pp. 20758 - 20761
Autores principales:	Petuškova, Jekaterina, Patil, Mahendra, Holle, Sigrid, Lehmann, Christian W., Thiel, Walter, Alcarazo, Manuel
Formato:	Artículo
Publicado:	American Chemical Society 12/28/2011
Materias:	Carbenes Organic synthesis Electron pairs Density functionals Ligands (Chemistry)
Acceso en línea:	Ver este registro en EBSCOhost