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Synthesis, Structure, and Reactivity of Carbene-Stabilized Phosphorus(III)-Centered Trications [LP].

Carbene-stabilized [LP] cations have been synthesized for the first time by a reaction between 1-chloro-2,3-bis(dialkylamino)cyclopropenium salts and P(SiMe). In addition, the first structural characterization of such an entity is reported. Consistent with the X-ray data, density functional calculat...

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Published in:Journal of the American Chemical Society Vol. 133; no. 51; pp. 20758 - 20761
Main Authors: Petuškova, Jekaterina, Patil, Mahendra, Holle, Sigrid, Lehmann, Christian W., Thiel, Walter, Alcarazo, Manuel
Format: Article
Published: American Chemical Society 12/28/2011
Subjects:
Carbenes
Organic synthesis
Electron pairs
Density functionals
Ligands (Chemistry)
Online Access:View this record in EBSCOhost