Aggregation of Donor Base Stabilized 2-Thienyllithium in a Single Crystal and in Solution: Distances from X-ray Diffraction and the Nuclear Overhauser Effect.

Various 2-thienyllithium derivatives were investigated in the solid state by X-ray diffraction and in solution by 2D NMR experiments. The determined structures of [(EtO)Li(CHS)] (1), [(THF)Li(CHS)] (2), [(DME)Li(CHS)] (3), [(TMEDA)Li(CHS)] (4), and [(PMDETA)Li(CHS)] (5) (DME = 1,2-dimethoxyethane, T...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 134; no. 2; pp. 1344 - 1352
Main Authors:	Granitzka, Markus, Pöppler, Ann-Christin, Schwarze, Eike K., Stern, Daniel, Schulz, Thomas, John, Michael, Herbst-Irmer, Regine, Pandey, Sushil K., Stalke, Dietmar
Format:	Article
Published:	American Chemical Society 1/18/2012
Subjects:	Optical diffraction X-rays Overhauser effect (Nuclear physics) Spectrum analysis Nitrogen Thiophenes Deuterium
Online Access:	View this record in EBSCOhost