Through-Bond versus Through-Space Coupling in Mixed-Valence Molecules: Observation of Electron Localization at the Single-Molecule Scale.

Scanning tunneling microscopy (STM) is used to study two dinuclear organometallic molecules, meta-Fe2 and para-Fe2, which have identical molecular formulas but differ in the geometry in which the metal centers are linked through a central phenyl ring. Both molecules show symmetric electron density w...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 3; pp. 1710 - 1715
Autores principales:	Quardokus, Rebecca C., Yuhui Lu, Wasio, Natalie A., Lent, Craig S., Justaud, Frederic, Lapinte, Claude, Kandel, S. Alex
Formato:	Artículo
Publicado:	American Chemical Society 1/25/2012
Materias:	Scanning tunneling microscopy Electron distribution Symmetry (Biology) Density functionals Oxidation Phenyl compounds Iron
Acceso en línea:	Ver este registro en EBSCOhost