Electron Paramagnetic Resonance and Mössbauer Spectroscopy and Density Functional Theory Analysis of a High-Spin' Fe-Oxo Complex.

High-spin Fe-oxo species are known to be kinetically competent oxidants in non-heme iron enzymes. The properties of these oxidants are not as well understood as the corresponding intermediate-spin oxidants of heme complexes. The present work gives a detailed characterization of the structurally simi...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 23; pp. 9775 - 9785
Autores principales:	Gupta, Rupal, Lacy, David C., Bominaar, Emile L., Borovik, A. S., Hendrich, Michael P.
Formato:	Artículo
Publicado:	American Chemical Society 6/13/2012
Materias:	Electron paramagnetic resonance spectroscopy Mössbauer spectroscopy Density functionals Oxidizing agents Iron compounds Oxo compounds
Acceso en línea:	Ver este registro en EBSCOhost