Redox-Active Scandium Oxide Cluster inside a Fullerene Cage: Spectroscopic, Voltammetric, Electron Spin Resonance Spectroelectrochemical, and Extended Density Functional Theory Study of ScO@C and Its Ion Radicals.

The clusterfullerene ScO@C with a mixed redox state of scandium was found to be an exciting molecule for endohedral electrochemistry as demonstrated by means of an in situ electron spin resonance (ESR) spectroelectrochemical study of the spin density distribution in its electrochemically generated c...

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Publicado en:	Journal of the American Chemical Society Vol. 134; no. 48; pp. 19607 - 19619
Autores principales:	Popov, Alexey A., Ning Chen, Pinzón, Julio R., Stevenson, Steven, Echegoyen, Luis A., Dunsch, Lothar
Formato:	Artículo
Publicado:	American Chemical Society 12/5/2012
Materias:	Scandium oxides Oxidation-reduction reaction Fullerenes Electron paramagnetic resonance spectroscopy Density functionals Radicals (Chemistry) Ions Electrochemistry
Acceso en línea:	Ver este registro en EBSCOhost