Transition-Metal-Free Direct Arylation: Synthesis of Halogenated 2-Amino-2'-hydroxy-1,1'-biaryls and Mechanism by DFT Calculations.

A transition-metal-free, regioselective direct aryl–aryl bond-forming process for the synthesis of halogenated 2-amino-2'-hydroxy-1,1'-biaryls that are currently either inaccessible or challenging to prepare using conventional methods is disclosed. The addition of ArMgX to an o-halonitrobenzene at l...

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Publicado en:	Journal of the American Chemical Society Vol. 135; no. 19; pp. 7086 - 7090
Autores principales:	Hongyin Gao, Ess, Daniel H., Yousufuddin, Muhammed, Kürti, László
Formato:	Artículo
Publicado:	American Chemical Society 5/15/2013
Materias:	Aromatic compound synthesis Arylation Density functional theory Transition metal catalysts Regioselectivity (Chemistry) Nitrobenzene Bond formation mechanism
Acceso en línea:	Ver este registro en EBSCOhost