Revisiting the Chemistry of the Actinocenes [(η-CH)An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(η-CH)An(L)] with Thorium (L = py, 4,4'-bipy, tBuNC, Rphen)
In stark contrast to uranocene, (Cot)Th reacts with neutral mono- or bidentate Lewis bases to give the bent sandwich complexes (Cot)Th(L) (L = py, 4,4'-bipy, tBuNC, phen, Mephen). DFT calculations in the gas phase show that, for both U and Th, formation of the bent compound (Cot)An(L) should be faci...
| Publicado en: | Journal of the American Chemical Society Vol. 135; no. 27; pp. 10003 - 10007 |
|---|---|
| Autores principales: | , , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
7/10/2013
|
| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=89430736&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 89430736 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 7/10/2013 vid: 135 iid: 27 pid: 997 pub: American Chemical Society artinfo: ui: 89430736 10.1021/ja4036626 ppf: 10003 ppct: 4 formats: tig: atl: Revisiting the Chemistry of the Actinocenes [(η-CH)An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(η-CH)An(L)] with Thorium (L = py, 4,4'-bipy, tBuNC, Rphen) aug: au: Berthet, Jean-Claude Thuéry, Pierre Garin, Nicolas Dognon, Jean-Pierre Cantat, Thibault Ephritikhine, Michel affil: CEA, IRAMIS, SIS2M, CNRS UMR 3299, CEA/Saclay, 91191 Gif-sur-Yvette, France su: Lewis bases Thorium compounds Uranium compounds Density functional theory Bent molecules Actinide elements Ligands (Chemistry) sug: subj: Lewis bases Thorium compounds Uranium compounds Density functional theory Bent molecules Actinide elements Ligands (Chemistry) ab: In stark contrast to uranocene, (Cot)Th reacts with neutral mono- or bidentate Lewis bases to give the bent sandwich complexes (Cot)Th(L) (L = py, 4,4'-bipy, tBuNC, phen, Mephen). DFT calculations in the gas phase show that, for both U and Th, formation of the bent compound (Cot)An(L) should be facile, the linear and bent forms being close in energy. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2013 holdings: @attributes: islocal: N |
|---|