Revisiting the Chemistry of the Actinocenes [(η-CH)An] (An = U, Th) with Neutral Lewis Bases. Access to the Bent Sandwich Complexes [(η-CH)An(L)] with Thorium (L = py, 4,4'-bipy, tBuNC, Rphen)

In stark contrast to uranocene, (Cot)Th reacts with neutral mono- or bidentate Lewis bases to give the bent sandwich complexes (Cot)Th(L) (L = py, 4,4'-bipy, tBuNC, phen, Mephen). DFT calculations in the gas phase show that, for both U and Th, formation of the bent compound (Cot)An(L) should be faci...

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Publicado en:	Journal of the American Chemical Society Vol. 135; no. 27; pp. 10003 - 10007
Autores principales:	Berthet, Jean-Claude, Thuéry, Pierre, Garin, Nicolas, Dognon, Jean-Pierre, Cantat, Thibault, Ephritikhine, Michel
Formato:	Artículo
Publicado:	American Chemical Society 7/10/2013
Materias:	Lewis bases Thorium compounds Uranium compounds Density functional theory Bent molecules Actinide elements Ligands (Chemistry)
Acceso en línea:	Ver este registro en EBSCOhost