β-Technetium Dichloride: Solid-State Modulated Structure, Electronic Structure, and Physical Properties.

A second polymorph of technetium dichloride, β-TcCl, has been synthesized from the reaction of Tc metal and chlorine in a sealed tube at 450 °C. The crystallographic structure and physical properties of β-TcCl have been investigated. The structure of β-TcCl consists of infinite chains of face sharin...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 135; no. 42; pp. 15955 - 15963
Main Authors:	Malliakas, Christos D., Poineau, Frederic, Johnstone, Erik V., Weck, Philippe F., Kim, Eunja, Scott, Brian L., Forster, Paul M., Kanatzidis, Mercouri G., Czerwinski, Kenneth R., Sattelberger, Alfred P.
Format:	Article
Published:	American Chemical Society 10/23/2013
Subjects:	Technetium Chlorides Electronic structure Crystallography Seebeck effect Electrical resistivity Single crystals Density functionals
Online Access:	View this record in EBSCOhost