A Dimethylgallium Boryl Complex and Its Methyllithium Addition Compound.
The three-coordinate complex MeGa[B-(NArCH)] (Ar = CHiPr-2,6) is accessible via a tandem Lewis acid-base metathesis protocol employing (THF)Li[B(NArCH)] and GaMe. It features a very short Ga-B bond of 2.067(3) A, which was further investigated by DFT calculations and the analysis of the electron den...
| Publicado en: | Journal of the American Chemical Society Vol. 136; no. 3; pp. 886 - 890 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
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American Chemical Society
1/22/2014
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=95065877&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 95065877 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 1/22/2014 vid: 136 iid: 3 pid: 997 pub: American Chemical Society artinfo: ui: 95065877 10.1021/ja4117318 ppf: 886 ppct: 4 formats: tig: atl: A Dimethylgallium Boryl Complex and Its Methyllithium Addition Compound. aug: au: Dettenrieder, Nicole Schädle, Christoph Maichle-Mössmer, Cäcilia Sirsch, Peter Anwander, Reiner affil: Institut für Anorganische Chemie, Auf der Morgenstelle 18, 72076 Tübingen, Germany su: Gallium compounds Methyllithium Electron density Density functionals Metathesis reactions Acid-base chemistry Coordination compounds sug: subj: Gallium compounds Methyllithium Electron density Density functionals Metathesis reactions Acid-base chemistry Coordination compounds ab: The three-coordinate complex MeGa[B-(NArCH)] (Ar = CHiPr-2,6) is accessible via a tandem Lewis acid-base metathesis protocol employing (THF)Li[B(NArCH)] and GaMe. It features a very short Ga-B bond of 2.067(3) A, which was further investigated by DFT calculations and the analysis of the electron density. Reaction of MeLi with MeGa[B- (NArCH)] forms tetrameric [LiMeGa{B(NArCH)}] with a "nanowheel" structure. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2014 holdings: @attributes: islocal: N |
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