A Dimethylgallium Boryl Complex and Its Methyllithium Addition Compound.

The three-coordinate complex MeGa[B-(NArCH)] (Ar = CHiPr-2,6) is accessible via a tandem Lewis acid-base metathesis protocol employing (THF)Li[B(NArCH)] and GaMe. It features a very short Ga-B bond of 2.067(3) A, which was further investigated by DFT calculations and the analysis of the electron den...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 3; pp. 886 - 890
Autores principales:	Dettenrieder, Nicole, Schädle, Christoph, Maichle-Mössmer, Cäcilia, Sirsch, Peter, Anwander, Reiner
Formato:	Artículo
Publicado:	American Chemical Society 1/22/2014
Materias:	Gallium compounds Methyllithium Electron density Density functionals Metathesis reactions Acid-base chemistry Coordination compounds
Acceso en línea:	Ver este registro en EBSCOhost