Mechanical Tunability via Hydrogen Bonding in Metal-Organic Frameworks with the Perovskite Architecture.

Two analogous metal-organic frameworks (MOFs) with the perovskite architecture, [C(NH)][Mn-(HCOO)] (1) and [(CH)NH][Mn(HCOO)] (2), exhibit significantly different mechanical properties. The marked difference is attributed to their distinct modes of hydrogen bonding between the A-site amine cation an...

Descripción completa

Detalles Bibliográficos

Publicado en:	Journal of the American Chemical Society Vol. 136; no. 22; pp. 7801 - 7805
Autores principales:	Wei Li, Thirumurugan, A., Barton, Phillip T., Zheshuai Lin, Henke, Sebastian, Yeung, Hamish H.-M., Wharmby, Michael T., Bithell, Erica G., Howard, Christopher J., Cheetham, Anthony K.
Formato:	Artículo
Publicado:	American Chemical Society 6/4/2014
Materias:	Metal-organic frameworks Structural frames Perovskite Hydrogen bonding Molecular association Crystal chemical bonds Thermal expansion
Acceso en línea:	Ver este registro en EBSCOhost