Mechanical Tunability via Hydrogen Bonding in Metal-Organic Frameworks with the Perovskite Architecture.

Two analogous metal-organic frameworks (MOFs) with the perovskite architecture, [C(NH)][Mn-(HCOO)] (1) and [(CH)NH][Mn(HCOO)] (2), exhibit significantly different mechanical properties. The marked difference is attributed to their distinct modes of hydrogen bonding between the A-site amine cation an...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 136; no. 22; pp. 7801 - 7805
Main Authors:	Wei Li, Thirumurugan, A., Barton, Phillip T., Zheshuai Lin, Henke, Sebastian, Yeung, Hamish H.-M., Wharmby, Michael T., Bithell, Erica G., Howard, Christopher J., Cheetham, Anthony K.
Format:	Article
Published:	American Chemical Society 6/4/2014
Subjects:	Metal-organic frameworks Structural frames Perovskite Hydrogen bonding Molecular association Crystal chemical bonds Thermal expansion
Online Access:	View this record in EBSCOhost