Imagen de Portada
Código QR

Coinage-Metal Mediated Ring Opening of cis-1,2-Dimethoxycyclopropane: Trends from the Gold, Copper, and Silver Fischer Carbene Bond Strength.

N-heterocyclic carbene (NHC) supported coinage metal cations proved to react in the gas phase with the electron-rich cis-l,2-dimethoxycydopropane. Upon Collision Induced Dissociation (CID), several spectrometric fragment-ion signals were observed, one corresponding to the recovery of the bare cation...

Descripción completa

Publicado en:Journal of the American Chemical Society Vol. 136; no. 26; pp. 9296 - 9308
Autores principales: Batiste, Laurent, Chen, Peter
Formato: Artículo
Publicado: American Chemical Society 7/2/2014
Materias:
Carbenes
Bond strengths
Heterocyclic compounds
Cations
Gas phase reactions
Density functional theory
Dissociation (Chemistry)
Moieties (Chemistry)
Acceso en línea:Ver este registro en EBSCOhost