An Intermediate Cobalt(IV) Nitrido Complex and its N-Migratory Insertion Product.

Low-temperature photolysis experiments (T = 10 K) on the tripodal azido complex [(BIMPN)Co(N)] ( l) were monitored by EPR spectroscopy and support the formation of an exceedingly reactive, high-valent Co nitrido species [(BIMPN)Co (N)] (2). Density functional theory calculations suggest a low-spin d...

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Bibliographic Details

Published in:	Journal of the American Chemical Society Vol. 136; no. 42; pp. 15072 - 15079
Main Authors:	Zolnhofer, Eva M., Käβ, Martina, Khusniyarov, Marat M., Heinemann, Frank W., Maron, Laurent, van Gaste, Maurice, Bill, Eckhard, Meyer, Karsten
Format:	Article
Published:	American Chemical Society 10/22/2014
Subjects:	Photolysis (Chemistry) Azido group Electron paramagnetic resonance spectroscopy Density functional theory Nitrides
Online Access:	View this record in EBSCOhost