Structural Characterization of CO-Inhibited Mo-Nitrogenase by Combined Application of Nuclear Resonance Vibrational Spectroscopy, Extended X-ray Absorption Fine Structure, and Density Functional Theory: New Insights into the Effects of CO Binding and the Role of the Interstitial Atom

The properties of CO-inhibited Azotobader vinelandii (Av) Mo-nitrogenase (Nase) have been examined by the combined application of nuclear resonance vibrational spectroscopy (NRVS), extended X-ray absorption fine structure (EXAFS), and density functional theory (DFT). Dramatic changes in the NRVS are...

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Publicado en:	Journal of the American Chemical Society Vol. 136; no. 45; pp. 15942 - 15955
Autores principales:	Scott, Aubrey D., Yan, Lifen, George, Simon J., Wang, Honexin, Cramer, Stephen P., Pelmenschikov, Vladimir, Guo, Yisong, Dapper, Christie H., Newton, William E., Yoda, Yoshitaka, Tanaka, Yoshihito
Formato:	Artículo
Publicado:	American Chemical Society 11/12/2014
Materias:	Nitrogenases Nuclear resonance reactions Vibrational spectra X-ray absorption Density functional theory Interstitial defects Atoms
Acceso en línea:	Ver este registro en EBSCOhost