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[Pd(μ-SbMe)(SbMe)]: A Pd(0) Tetrahedron with μ-Bridging Trimethylantimony Ligands.

The palladium(II) chlorostibine complex [PdCl(SbMeCl)] has a dimeric structure in the solid state, stabilized by hyper-coordination at the Lewis amphoteric Sb centers. Reaction with 8 equiv of MeLi forms [Pd(μ-SbMe)(SbMe)], whose structure comprises a tetrahedral Pd(0) core with four terminal SbMe l...

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Published in:Journal of the American Chemical Society Vol. 138; no. 22; pp. 6964 - 6968
Main Authors: Benjamin, Sophie L., Krämer, Tobias, Levason, William, Light, Mark E., Macgregor, Stuart A., Reid, Gillian
Format: Article
Published: American Chemical Society 6/8/2016
Subjects:
Palladium
Tetrahedra
Lewis bases
Density functional theory
Ligands (Chemistry)
Coordination compounds
Ligand exchange reactions
Online Access:View this record in EBSCOhost