Titanium-Catalyzed Dehydrocoupling of Silanes: Direct Conversion of Primary Monosilanes to Titanium(0) Oligosilane Complexes with Agostic α-Sib-H… Ti Interactions.
The article focuses on the role of the chemical compound titanium(II) alkyl TiMe(dmpe) as a catalyst for the dehydrogenative oligomerization of primary arylsilanes. It was found that treatment of solutions of the compound with the compound PhSiH yields a diamagnetic species of the stoichiometric com...
| Publicado en: | Journal of the American Chemical Society Vol. 129; no. 7; pp. 1860 - 1862 |
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| Autores principales: | , , |
| Formato: | Artículo |
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American Chemical Society
2/21/2007
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| Acceso en línea: | Ver este registro en EBSCOhost |
| fields | @attributes: recordID: 1 pdfLink: plink: https://search.ebscohost.com/login.aspx?direct=true&db=hlh&AN=24245896&site=ehost-live header: @attributes: shortDbName: hlh uiTerm: 24245896 longDbName: Humanities International Complete uiTag: AN controlInfo: bkinfo: jinfo: jid: 00027863 ACS jtl: Journal of the American Chemical Society issn: 00027863 maglogo: N pubinfo: dt: 2/21/2007 vid: 129 iid: 7 pid: 997 pub: American Chemical Society artinfo: ui: 24245896 10.1021/ja067503a ppf: 1860 ppct: 2 formats: tig: atl: Titanium-Catalyzed Dehydrocoupling of Silanes: Direct Conversion of Primary Monosilanes to Titanium(0) Oligosilane Complexes with Agostic α-Sib-H… Ti Interactions. aug: au: Spencer, Michael D. Shelby, Quinetta D. Girolami, Gregory S. affil: School of Chemical Sciences, University of Illinois, Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801. su: Organotitanium compounds Catalysts Dehydrogenation Silane compounds Organosulfur compounds Stoichiometry sug: subj: Organotitanium compounds Catalysts Dehydrogenation Silane compounds Organosulfur compounds Stoichiometry ab: The article focuses on the role of the chemical compound titanium(II) alkyl TiMe(dmpe) as a catalyst for the dehydrogenative oligomerization of primary arylsilanes. It was found that treatment of solutions of the compound with the compound PhSiH yields a diamagnetic species of the stoichiometric compound which can be isolated as a purple solid. pubtype: Academic Journal doctype: Article src: R language: English refInfo: copyright: @attributes: flag: Y dt: @attributes: year: 2007 holdings: @attributes: islocal: N |
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