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Titanium-Catalyzed Dehydrocoupling of Silanes: Direct Conversion of Primary Monosilanes to Titanium(0) Oligosilane Complexes with Agostic α-Sib-H… Ti Interactions.

The article focuses on the role of the chemical compound titanium(II) alkyl TiMe(dmpe) as a catalyst for the dehydrogenative oligomerization of primary arylsilanes. It was found that treatment of solutions of the compound with the compound PhSiH yields a diamagnetic species of the stoichiometric com...

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Publicado en:Journal of the American Chemical Society Vol. 129; no. 7; pp. 1860 - 1862
Autores principales: Spencer, Michael D., Shelby, Quinetta D., Girolami, Gregory S.
Formato: Artículo
Publicado: American Chemical Society 2/21/2007
Materias:
Organotitanium compounds
Catalysts
Dehydrogenation
Silane compounds
Organosulfur compounds
Stoichiometry
Acceso en línea:Ver este registro en EBSCOhost
Sumario:The article focuses on the role of the chemical compound titanium(II) alkyl TiMe(dmpe) as a catalyst for the dehydrogenative oligomerization of primary arylsilanes. It was found that treatment of solutions of the compound with the compound PhSiH yields a diamagnetic species of the stoichiometric compound which can be isolated as a purple solid.