Titanium-Catalyzed Dehydrocoupling of Silanes: Direct Conversion of Primary Monosilanes to Titanium(0) Oligosilane Complexes with Agostic α-Sib-H… Ti Interactions.

The article focuses on the role of the chemical compound titanium(II) alkyl TiMe(dmpe) as a catalyst for the dehydrogenative oligomerization of primary arylsilanes. It was found that treatment of solutions of the compound with the compound PhSiH yields a diamagnetic species of the stoichiometric com...

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Publicado en:	Journal of the American Chemical Society Vol. 129; no. 7; pp. 1860 - 1862
Autores principales:	Spencer, Michael D., Shelby, Quinetta D., Girolami, Gregory S.
Formato:	Artículo
Publicado:	American Chemical Society 2/21/2007
Materias:	Organotitanium compounds Catalysts Dehydrogenation Silane compounds Organosulfur compounds Stoichiometry
Acceso en línea:	Ver este registro en EBSCOhost