Continuous Wave Photolysis Magnetic Field Effect Investigations with Free and Protein-Bound Alkylcobalamins.

The activation of the Co-C bond in adenosylcobalamin-dependent enzymes generates a singlet-born Co-adenosyl radical pair. Two of the salient questions regarding this process are: (1) What is the origin of the considerable homolysis rate enhancement achieved by this class of enzyme? (2) Are the react...

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Publicado en:	Journal of the American Chemical Society Vol. 131; no. 47; pp. 17246 - 17254
Autores principales:	Jones, Alex R., Woodward, Jonathan R., Scrutton, Nigel S.
Formato:	Artículo
Publicado:	American Chemical Society 12/2/2009
Materias:	Enzymes Photochemistry Magnetic fields Field theory (Physics) Proteins
Acceso en línea:	Ver este registro en EBSCOhost