Continuous Wave Photolysis Magnetic Field Effect Investigations with Free and Protein-Bound Alkylcobalamins.
The activation of the Co-C bond in adenosylcobalamin-dependent enzymes generates a singlet-born Co-adenosyl radical pair. Two of the salient questions regarding this process are: (1) What is the origin of the considerable homolysis rate enhancement achieved by this class of enzyme? (2) Are the react...
| Publicado en: | Journal of the American Chemical Society Vol. 131; no. 47; pp. 17246 - 17254 |
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| Autores principales: | , , |
| Formato: | Artículo |
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American Chemical Society
12/2/2009
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |