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Continuous Wave Photolysis Magnetic Field Effect Investigations with Free and Protein-Bound Alkylcobalamins.

The activation of the Co-C bond in adenosylcobalamin-dependent enzymes generates a singlet-born Co-adenosyl radical pair. Two of the salient questions regarding this process are: (1) What is the origin of the considerable homolysis rate enhancement achieved by this class of enzyme? (2) Are the react...

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Published in:Journal of the American Chemical Society Vol. 131; no. 47; pp. 17246 - 17254
Main Authors: Jones, Alex R., Woodward, Jonathan R., Scrutton, Nigel S.
Format: Article
Published: American Chemical Society 12/2/2009
Subjects:
Enzymes
Photochemistry
Magnetic fields
Field theory (Physics)
Proteins
Online Access:View this record in EBSCOhost