Directly Pd(II)-Bridged Porphyrin Belts with Remarkable Curvatures.

A β,β'-doubly 2,6-pyridylene-bridged porphyrin dimer and trimer were prepared by Suzuki-Miyaura coupling reactions and confirmed to have largely bent structures. These oligopor- phyrins were readily metalated via meso-C-H bond activation with the assistance of the pyridyl nitrogen atoms to produce t...

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Publicado en:Journal of the American Chemical Society Vol. 132; no. 34; pp. 11868 - 11870
Autores principales: Jianxin Song, Aratani, Naoki, Ji Haeng Heo, Dongho Kim, Shinokubo, Hiroshi, Osuka, Atsuhiro
Formato: Artículo
Publicado: American Chemical Society 9/1/2010
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Acceso en línea:Ver este registro en EBSCOhost