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Redox-Active Scandium Oxide Cluster inside a Fullerene Cage: Spectroscopic, Voltammetric, Electron Spin Resonance Spectroelectrochemical, and Extended Density Functional Theory Study of ScO@C and Its Ion Radicals.

The clusterfullerene ScO@C with a mixed redox state of scandium was found to be an exciting molecule for endohedral electrochemistry as demonstrated by means of an in situ electron spin resonance (ESR) spectroelectrochemical study of the spin density distribution in its electrochemically generated c...

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Published in:Journal of the American Chemical Society Vol. 134; no. 48; pp. 19607 - 19619
Main Authors: Popov, Alexey A., Ning Chen, Pinzón, Julio R., Stevenson, Steven, Echegoyen, Luis A., Dunsch, Lothar
Format: Article
Published: American Chemical Society 12/5/2012
Subjects:
Scandium oxides
Oxidation-reduction reaction
Fullerenes
Electron paramagnetic resonance spectroscopy
Density functionals
Radicals (Chemistry)
Ions
Electrochemistry
Online Access:View this record in EBSCOhost