Control of Vertex Geometry, Structure Dimensionality, Functionality, and Pore Metrics in the Reticular Synthesis of Crystalline Metal—Organic Frameworks and Polyhedra.
Metal-organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M(CO) (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and cryst...
| Publicado en: | Journal of the American Chemical Society Vol. 130; no. 35; pp. 11650 - 11662 |
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| Autores principales: | , , , , |
| Formato: | Artículo |
| Publicado: |
American Chemical Society
9/3/2008
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| Materias: | |
| Acceso en línea: | Ver este registro en EBSCOhost |
| Sumario: | Metal-organic polyhedra and frameworks (MOPs and MOFs) were prepared by linking square units M(CO) (M = Cu and Zn) with a variety of organic linkers designed to control the dimensionality (periodicity) and topology of the resulting structures. We describe the preparation, characterization, and crystal structures of 5 new MOPs and 11 new MOFs (termed MOP-14, -15, -17, -23, -24 and MOF-114, -115,-116,-117,-118,-119,-222,-601,-602,-603,-604)and show how their structures are related to the shape and functionality of the building blocks. The gas uptake behaviors of MOP-23 and MOF-601 to -603 are also presented as evidence that these structures have permanent porosity and rigid architectures. |
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